当前位置: X-MOL 学术Eur. J. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
4‐Aryl‐2‐Imino‐1,3‐Dithiolanes from the Room Temperature Coupling of Sodium Dithiocarbamates with Sulfonium Salts
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-02-23 , DOI: 10.1002/ejoc.202100124
Giulio Bresciani 1 , Fabio Marchetti 1 , Gianluca Ciancaleoni 1 , Guido Pampaloni 2
Affiliation  

A new and easy synthesis of 4‐aryl‐2‐imino‐1,3‐dithiolanes was performed in water/dichloromethane starting from simple precursors, i. e., dithiocarbamate and sulfonium bromide salts. Various possible mechanism pathways were investigated by DFT calculations.
image


中文翻译:

二硫代氨基甲酸钠与with盐在室温下的偶联反应中的4-芳基-2-亚氨基-1,3-二硫杂环戊烷

从简单的前体开始,在水/二氯甲烷中进行了一种新的,易于合成的4-芳基-2-亚氨基-1,3-二硫杂环戊烷。例如,二硫代氨基甲酸盐和溴化salts盐。通过DFT计算研究了各种可能的机理途径。
图像
更新日期:2021-03-08
down
wechat
bug