The triphenylmethane derivative malachite green (tpm_MaG) despite repeated prohibitions but is frequently detected in aquatic environment and draws emerging attention because of the potential poisonous effects. The polyaniline/persulfate with ultrasound catalysis (US/PANI-PS) was developed for tpm_MaG removal. The effects of 12 factors and the optimization by response surface methodology (RSM) for tpm_FG removal were evaluated based on the pseudo-first-kinetics (k_obs). From free radical inhibition, the ratios of active species in US/PANI-PS (δ₁₁ = 0.355, δ₁₂ = 0.593) were close to that in US-PS (δ₂₁ = 0.346, δ₂₂ = 0.586) and different to that in PANI-PS and PS systems. A possible degradation pathway (hydroxylation, N-demethylation, deamination, and open-benzene ring) was explored by gas chromatography-mass spectrometer (GC/MS) and high performance liquid chromatography-mass spectrometer (HPLC-MS). The designed reactor involving the US-driven PANI was simulated by acoustic-piezoelectric interaction. From cavitation calculations, the estimated effective-mean temperature at bubble-water interface had little increasing (from 704 K to 711 K) after adding the PANI, however, the adsorption capacity of tpm_MaG in reactive zone decreased from 0.0891 μM to 0.0787 μM. The mechanism (PANI hot turbo-micromotors) with US/PANI-PS was proposed. The tpm_MaG was removed with a low treatment cost of 2.81 $⋅m⁻³ (the EE/O value 18.29 kWh⋅m⁻³) by US/PANI-PS, presenting a cost-effective treating process. The reusability tests and characterizations (contact angle, X-ray diffraction (XRD), and scanning electron microscope (SEM)) further confirmed the stability of PANI.

三苯甲烷衍生物孔雀石绿（tpm _MaG）尽管屡禁不止，但在水生环境中经常被发现，并由于潜在的毒性作用而引起人们的关注。开发了具有超声催化作用的聚苯胺/过硫酸盐（US / PANI-PS），用于去除tpm _MaG。基于伪第一动力学（k _obs）评估了12个因素的影响以及通过响应面方法（RSM）进行的tpm _FG去除的优化。从自由基的抑制，活性物种的在US / PANI-PS的比率（δ ₁₁  = 0.355，Δ ₁₂  = 0.593）被接近，在US-PS（δ ₂₁  = 0.346，δ ₂₂ = 0.586），并且与PANI-PS和PS系统中的不同。通过气相色谱-质谱仪（GC / MS）和高效液相色谱-质谱仪（HPLC-MS）探索了可能的降解途径（羟基化，N-脱甲基化，脱氨基和开苯环）。通过声-压电相互作用模拟了由美国驱动的PANI设计的反应堆。从空化计算来看，添加PANI后，气泡-水界面的估计有效平均温度几乎没有增加（从704 K到711 K），但是，反应区内tpm _MaG的吸附容量从_0.0891μM降低到0.0787μM。提出了带有US / PANI-PS的机构（PANI热涡轮微电机）。去除了tpm _MaG，处理成本低至2.81 $⋅mUS / PANI-PS的^-3（EE / O值为18.29 kWh·m ^-3），提出了一种具有成本效益的处理方法。可重用性测试和表征（接触角，X射线衍射（XRD）和扫描电子显微镜（SEM））进一步证实了PANI的稳定性。