Emerging Spacers‐Based Ligands for Supramolecular Coordination Complexes,The Chemical Record

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Emerging Spacers‐Based Ligands for Supramolecular Coordination Complexes
The Chemical Record ( IF 7.0 ) Pub Date : 2021-02-22 , DOI: 10.1002/tcr.202000150
Isha Mishra ₁ , Mamina Bhol ₁ , Palanisamy Kalimuthu ₂ , Malaichamy Sathiyendiran ₁

Affiliation

The design and self‐assembly of supramolecular coordination complexes (SCCs) i. e., discrete cyclic metalloarchitectures such as cycles, cages, mesocates, and helicates with desired size, shape, and properties have been increasing exponentially owing to their potential applications in molecular sensors, molecular cargos, molecular recognition, and catalysis. The introduction of the organic motifs and metal complexes as a spacer provides functionality to the metalloarchitecture. This review mainly focusses on newly evolving spacer based ligands employed to yield simple to high‐order metallosupramolecular assemblies using straight‐forward approaches. The new spacers including corannulene, organic cyclic framework, bicyclic organic motifs, aliphatic chain, metalloligands, triarylboron, BODIPY, azaphosphatrane, phosphine, and thio/selenophosphates offer a great set of properties and in‐built functionalities to the metalloarchitectures which are discussed in this review.

中文翻译：

新兴的基于间隔物的配体用于超分子配位化合物

超分子配位化合物（SCC）的设计和自组装i。例如，具有潜在尺寸，形状和特性的离散的环状金属结构，例如循环，笼子，中链和螺旋结构，由于它们在分子传感器，分子货物，分子识别和催化中的潜在应用而呈指数增长。有机基序和金属配合物作为间隔基的引入为金属建筑提供了功能。这篇综述主要集中在新发展的基于间隔基的配体上，这些配体用于使用简单方法生成简单到高阶的金属超分子组装体。新的间隔基包括：氢化萘，有机环状骨架，双环有机基序，脂肪族链，金属配体，三芳基硼，BODIPY，氮杂磷杂环戊烷，膦，

更新日期：2021-03-11

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