The review summarizes and systimatizes data on the stereochemistry, mechanisms and applications of electrophilic reactions of organophosphorus compounds. Asymmetric versions of the Michaelis – Arbuzov, Michaelis – Becker, Hirao, Staudinger, Pudovik and other reactions are considered. Key issues of asymmetric electrophilic catalysis are discussed. The reaction conditions, catalytic systems and structures of the reaction products are presented. Asymmetric electrophilic reactions are used in organic synthesis and in studies of the mechanisms of chemical processes involving organophosphorus compounds.

The bibliography includes 209 references.

中文翻译：

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有机磷化合物亲电反应的立体化学，机理及应用

该综述总结并系统化了有机磷化合物亲电反应的立体化学，机理和应用方面的数据。考虑了米高斯-阿尔布佐夫，米高斯-贝克尔，平尾，施陶丁格，普多维克和其他反应的不对称形式。讨论了不对称亲电催化的关键问题。介绍了反应条件，催化体系和反应产物的结构。不对称亲电反应用于有机合成和涉及有机磷化合物的化学过程机理的研究。

参考书目包括209个参考文献。