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Preparation of macrocyclic musks via olefin metathesis: comparison with classical syntheses and recent advances
Russian Chemical Reviews ( IF 7.0 ) Pub Date : 2020-03-31 , DOI: 10.1070/rcr4930
Adrian Sytniczuk , Mariusz Milewski , Anna Kajetanowicz , Karol Grela

Recent advances in the synthesis of macrocycles with musk scent via catalytic olefin metathesis are presented with a particular emphasis on advantages offered by the metathesis technology. The review includes short historical background about musks and olefin metathesis to introduce the subject. Substantial emphasis is given on ring-closing metathesis (RCM) as a tool for the synthesis of cyclic compounds such as civetone, muscone, exaltolide, ambrettolide/isoambrettolide, and yuzu lactone.

The bibliography includes 106 references.



中文翻译:

烯烃复分解制备大环麝香:与经典合成的比较及最新进展

介绍了通过催化烯烃复分解合成具有麝香气味的大环化合物的最新进展,特别强调了复分解技术提供的优势。该评论包括关于麝香和烯烃复分解的简短历史背景以介绍该主题。重点强调了闭环复分解 (RCM) 作为合成环状化合物的工具,例如 civetone、muscone、exaltolide、ambretolide/isoambrettolide 和柚子内酯。

参考书目包括 106 篇参考文献。

更新日期:2020-03-31
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