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Amphiphilic multicomponent molecular brushes
Russian Chemical Reviews ( IF 7.0 ) Pub Date : 2019-12-02 , DOI: 10.1070/rcr4870
Ivan V. Ivanov 1 , Tamara K. Meleshko 1 , Anna V. Kashina 1 , Alexander V. Yakimansky 1, 2
Affiliation  

Multicomponent molecular brushes containing amphiphilic polymer moieties are promising objects of research of macromolecular chemistry. The development of stimulus-responsive systems sensitive to changes in environmental parameters, based on the molecular brushes, opens up new possibilities for their applications in medicine, biochemistry and microelectronics. The review presents the current understanding of the structures of main types of amphiphilic multicomponent brushes, depending on the chemical nature and type of coupling of the backbone and side chains. The approaches to the controlled synthesis of multicomponent molecular brushes of different architecture are analyzed. Self-assembly processes of multicomponent molecular brushes in selective solvents are considered.

The bibliography includes 259 references.



中文翻译:

两亲性多组分分子刷

含有两亲聚合物部分的多组分分子刷是大分子化学研究的有前途的对象。基于分子刷开发对环境参数变化敏感的刺激响应系统,为其在医学、生物化学和微电子学中的应用开辟了新的可能性。该综述介绍了目前对主要类型的两亲多组分刷的结构的理解,这取决于主链和侧链的化学性质和偶联类型。分析了不同结构的多组分分子刷的可控合成方法。考虑了多组分分子刷在选择性溶剂中的自组装过程。

参考书目包括 259 篇参考文献。

更新日期:2019-12-02
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