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In-situ fabrication of ZnO nanoparticles sensors based on gas-sensing electrode for ppb-level H2S detection at room temperatureProject supported by the National Natural Science Foundation of China (Grant Nos. 11904209 and 61904098), the Natural Science Foundation of Shandong Province, China (Grant No. ZR2019QF018), and Higher Education Research and Development Program of Shandong Province, China (Grant No. J18KA242).
Chinese Physics B ( IF 1.7 ) Pub Date : 2021-02-06 , DOI: 10.1088/1674-1056/abcf46
Jing-Yue Xuan 1 , Guo-Dong Zhao 1 , Xiao-Bo Shi 2 , Wei Geng 1 , Heng-Zheng Li 1 , Mei-Ling Sun 1 , Fu-Chao Jia 1 , Shu-Gang Tan 1 , Guang-Chao Yin 1 , Bo Liu 1
Affiliation  

The zinc oxide (ZnO) nanoparticles (NPs) sensors were prepared in-situ on the gas-sensing electrodes by a one-step simple sol-gel method for the detection of hydrogen sulfide (H2S) gas. The sphere-like ZnO NPs were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), x-ray diffraction (XRD), energy dispersive x-ray analysis (EDX), and their H2S sensing performance were measured at room temperature. Testing results indicate that the ZnO NPs exhibit excellent response to H2S gas at room temperature. The response value of the optimal sample to 750 ppb H2S is 73.3%, the detection limit reaches to 30 ppb, and the response value is 7.5%. Furthermore, the effects of the calcining time and thickness of the film on the gas-sensing performance were investigated. Both calcining time and film thickness show a negative correlation with the H2S sensing performance. The corresponding reaction mechanism of H2S detection was also discussed.



中文翻译:

国家自然科学基金项目(11904209和61904098)、山东省自然科学基金资助项目(批准号ZR2019QF018)和山东省高等教育研究发展计划(批准号J18KA242)。

通过一步简单的溶胶-凝胶法在气敏电极上原位制备氧化锌(ZnO)纳米颗粒(NPs)传感器,用于检测硫化氢(H 2 S)气体。采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、能量色散X射线分析(EDX)对球形ZnO纳米颗粒进行表征,并测量其H 2 S传感性能在室温下。测试结果表明,ZnO NPs在室温下对 H 2 S 气体表现出优异的响应。最佳样品对 750 ppb H 2的响应值S为73.3%,检出限达到30 ppb,响应值为7.5%。此外,还研究了煅烧时间和薄膜厚度对气敏性能的影响。煅烧时间和薄膜厚度均与H 2 S 传感性能呈负相关。还讨论了H 2 S检测的相应反应机理。

更新日期:2021-02-06
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