Biobased C6-Furans in Organic Synthesis and Industry: Cycloaddition Chemistry as a Key Approach to Aromatic Building Blocks,ACS Sustainable Chemistry & Engineering

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Biobased C6-Furans in Organic Synthesis and Industry: Cycloaddition Chemistry as a Key Approach to Aromatic Building Blocks
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2021-02-16 , DOI: 10.1021/acssuschemeng.0c09229
Fedor A. Kucherov ₁ , Leonid V. Romashov ₁ , Gleb M. Averochkin ₁ , Valentine P. Ananikov ₁

Affiliation

Rapid development in the area of cellulose biomass conversion to furanic platform chemicals has led to expectations of their valuable practical use. Impressive research progress in this direction has resulted in several achievements but at the same time identified a key challenge—the necessity to produce aromatic compounds. In this perspective, we analyze the current stage of development of the furanics-to-benzene conversion process (F2B process) in connection with a bioderived route to aromatic compounds. Cycloaddition reactions between bioderived C₆-furans as diene components and alkene/alkyne units are discussed in detail, followed by considering the subsequent aromatization reaction. Progress in the development of the F2B process and future challenges are outlined in this perspective. The key role of the F2B process in the overall biomass to aromatics transformation is discussed in view of the implementation of carbon neutral sustainable technologies in practice.

中文翻译：

有机合成和工业中基于生物的C _6-呋喃：环加成化学作为芳烃基团的关键方法

纤维素生物质转化为呋喃平台化学品领域的快速发展导致人们对其有价值的实际应用产生了期望。在这个方向上令人印象深刻的研究进展取得了多项成就，但同时也确定了一个关键挑战，即生产芳香族化合物的必要性。从这个角度出发，我们分析了与生物衍生途径合成芳族化合物有关的呋喃基苯转化工艺（F2B工艺）的发展现状。生物衍生的C ₆之间的环加成反应详细讨论了以呋喃为二烯组分和烯烃/炔烃单元的方法，然后考虑了随后的芳构化反应。此观点概述了F2B流程开发的进展和未来的挑战。鉴于实践中碳中和可持续技术的实施，讨论了F2B过程在整个生物质向芳烃转化中的关键作用。

更新日期：2021-03-01

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