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Controlling Radical Relay Processes with Visible Light
Chem ( IF 23.5 ) Pub Date : 2021-02-11 , DOI: 10.1016/j.chempr.2021.01.014 Andrey Shatskiy , Jian-Quan Liu , Markus D. Kärkäs
中文翻译:
用可见光控制自由基中继过程
更新日期:2021-02-11
Chem ( IF 23.5 ) Pub Date : 2021-02-11 , DOI: 10.1016/j.chempr.2021.01.014 Andrey Shatskiy , Jian-Quan Liu , Markus D. Kärkäs
Harnessing free radical intermediates for selective functionalization of organic compounds has been widely demonstrated under photocatalytic conditions requiring a distinct photocatalyst. In this issue of Chem, Seo, Chang, and co-workers demonstrate an alternative photocatalyst-free light-mediated approach that allows efficient amidation of aldehydes via N-centered radical intermediate.
中文翻译:
用可见光控制自由基中继过程
在需要独特光催化剂的光催化条件下,已广泛证明了利用自由基中间体来选择性官能化有机化合物。在本期《化学》杂志中,Seo,Chang和他的同事展示了一种无光催化剂的替代光导方法,该方法可通过N中心自由基中间体有效地醛化酰胺。