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Deprotection of the Carbazole Pmb Group Using Hypervalent Iodine Reagent Combined with
Heterocycles ( IF 0.8 ) Pub Date : 2021-02-08 , DOI: 10.3987/com-20-s(k)46
Tomohiro Maegawa , Kana Yoshikawa , Takanori Tabata , Kazuma Fujimura , Natsumi Kuraoka , Akira Nakamura , Yasuyoshi Miki

We developed a novel method for deprotecting the N-PMB group of carbazoles. The combination of PhI(OAc)2 and N-hydroxyphthalimide cleaved the N-PMB group with moderate to good yields depending on the substituents on the carbazole ring.

中文翻译:

高价碘试剂与咔唑Pmb基团的脱保护

我们开发了一种用于保护咔唑N -PMB基团的新型方法PhI(OAc)2N-羟基邻苯二甲酰亚胺的组合以中等至良好的产率裂解N -PMB基团,具体取决于咔唑环上的取代基。
更新日期:2021-03-23
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