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Synthesis of Azepino[1,2‐a]indole‐10‐amines via [6+1] Annulation of Ynenitriles with Reformatsky Reagent
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-02-03 , DOI: 10.1002/ejoc.202100021 Ryoya Iioka 1 , Kohei Yorozu 2 , Yoko Sakai 2 , Rika Kawai 2 , Noriyuki Hatae 3 , Katsuki Takashima 4 , Genzoh Tanabe 5 , Hiroaki Wasada 6 , Mitsuhiro Yoshimatsu 7
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-02-03 , DOI: 10.1002/ejoc.202100021 Ryoya Iioka 1 , Kohei Yorozu 2 , Yoko Sakai 2 , Rika Kawai 2 , Noriyuki Hatae 3 , Katsuki Takashima 4 , Genzoh Tanabe 5 , Hiroaki Wasada 6 , Mitsuhiro Yoshimatsu 7
Affiliation
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Scandium‐ or hafnium‐catalyzed [6+1] annulation reactions of 2‐cyano‐1‐propargyl‐ and 2‐alkynyl‐1‐cyanomethyl‐indoles with Reformatsky reagent delivered 8‐ and 9‐substituted‐azepino[1,2‐a]indole amines in good to high yields.
中文翻译：
通过Reformatsky试剂通过[6 + 1]腈腈合成Azepino [1,2-a]吲哚-10-胺
Re或ha催化的2-氰基-1-炔丙基和2-炔基-1-氰基甲基吲哚的Re [6 + 1]环化反应与Reformatsky试剂一起提供8和9-取代的氮杂环庚烷[1,2-a]吲哚胺的产率高到高。
更新日期：2021-03-08
中文翻译：
通过Reformatsky试剂通过[6 + 1]腈腈合成Azepino [1,2-a]吲哚-10-胺
Re或ha催化的2-氰基-1-炔丙基和2-炔基-1-氰基甲基吲哚的Re [6 + 1]环化反应与Reformatsky试剂一起提供8和9-取代的氮杂环庚烷[1,2-a]吲哚胺的产率高到高。
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