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Dynamics studied by Quasielastic Neutron Scattering (QENS)
Adsorption ( IF 3.3 ) Pub Date : 2021-02-02 , DOI: 10.1007/s10450-020-00295-4
Margarita Kruteva

Quasielastic neutron scattering (QENS) allows measurement of the molecular displacements in time and space, from pico- to tens of nanoseconds and from Ångstroms to nanometers, respectively. The method probes dynamics from fast vibrational modes down to slow diffusive motion. Every scattering experiment leads to a dynamic structure factor \(S\left( {\vec Q,\omega } \right)\) or its spatial and temporal Fourier transform (van Hove correlation function \(G\left( {\vec r,t} \right)\)). This shows exactly where the atoms are and how they move. In this manuscript the basics of the QENS method are presented and a few examples highlighting the potentials of QENS are given: (i) diffusion of liquids and gases in nano- and mesoporous materials; (ii) hydrogen dynamics in a high temperature polymer electrolyte fuel cell (HT-PEFC) and (iii) influence of the surface interactions on polymer dynamics in nanopores.



中文翻译:

准弹性中子散射(QENS)研究的动力学

准弹性中子散射(QENS)可以测量时间和空间上的分子位移,分别从皮秒到几十纳秒,从埃到几纳米。该方法探测从快速振动模式到慢速扩散运动的动力学。每个散射实验都会导致动态结构因子\(S \ left({\ vec Q,\ omega} \ right)\)或其时空傅立叶变换(van Hove相关函数\(G \ left({\ vec r ,t} \ right)\))。这准确地显示了原子在哪里以及它们如何移动。在本手稿中,介绍了QENS方法的基础,并列举了一些突出QENS潜力的例子:(i)液体和气体在纳米和中孔材料中的扩散;(ii)高温聚合物电解质燃料电池(HT-PEFC)中的氢动力学,以及(iii)表面相互作用对纳米孔中聚合物动力学的影响。

更新日期:2021-02-03
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