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4-Cyano-3-oxotetrahydrothiophene (c-THT): An Ideal Acrylonitrile Anion Equivalent
SynOpen ( IF 2.0 ) Pub Date : 2021-02-01 , DOI: 10.1055/s-0040-1706019 Stellios Arseniyadis 1 , François Richard 1 , Carlos Mateos 2
中文翻译：
4-氰基-3-氧代四氢噻吩（c-THT）：理想的丙烯腈阴离子当量
更新日期：2021-02-02
SynOpen ( IF 2.0 ) Pub Date : 2021-02-01 , DOI: 10.1055/s-0040-1706019 Stellios Arseniyadis 1 , François Richard 1 , Carlos Mateos 2
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4-Cyano-3-oxotetrahydrothiophene (c-THT) has much more to offer than just a platform to various heterocyclic scaffolds. This solid, bench-stable and commercially available reagent can be readily transformed into thioglycolic acid and acrylonitrile upon simple addition of a hydroxide anion. This interesting feature enables its use as a particularly versatile acrylonitrile anion surrogate.
中文翻译：
4-氰基-3-氧代四氢噻吩（c-THT）：理想的丙烯腈阴离子当量
4-氰基-3-氧代四氢噻吩（c-THT）不仅提供各种杂环支架的平台，还提供更多的功能。只需添加氢氧根阴离子，即可轻松将这种固体，台式稳定的市售试剂转化为巯基乙酸和丙烯腈。这个有趣的功能使其可以用作特别通用的丙烯腈阴离子替代物。
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