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Investigation of Physicochemical Properties of Initial Components for Polyelectrolyte Complex – Reagent for Oil and Gas Production
Chemistry and Technology of Fuels and Oils ( IF 0.6 ) Pub Date : 2021-02-01 , DOI: 10.1007/s10553-021-01205-2
R. S. Begalieva , I. N. Kulyashova , Zh. E. Dzhakupova , A. D. Badikova , A. G. Mustafin

The physicochemical properties of the initial components, poly-N,N-dimethyl-N,N-diallylammonium chloride, lignosulfonate, and polyelectrolyte complexes based on them, were studied. Optimal conditions and initial compounds were selected for polymerization of poly-N,N-dimethyl-N,N-diallylammonium chloride. The experiments were modeled with the STATISTICA 13 software package. The results from determination of the particle size of the samples of poly-N,N-dimethyl-N,N-diallylammonium chloride by laser diffraction are presented. Comparative analysis was made of the composition of the functional groups by means of the IR spectra of lignosulfonate sulfite and neutral sulfite methods of cellulose production A comparative analysis of the composition of the functional groups based on the IR spectra of lignosulfonate in the sulfite and neutral-sulfite method of cellulose production was undertaken. Potentiometric titration was used to study possible complexation of the lignosulfonate with Fe(77) ions and a polyelectrolyte complex based on modified lignosulfonate and poly-N,N-dimethyl-N,N-diallylammonium chloride. The effect of samples of the obtained polyelectrolyte complex on the filtration properties of drilling mud under aggressive temperature conditions was studied.



中文翻译:

聚电解质复合物初始组分理化性质的研究-油气生产试剂

研究了初始成分聚-N,N-二甲基-N,N-二烯丙基氯化铵,木质素磺酸盐和基于它们的聚电解质复合物的理化性质。选择最佳条件和初始化合物用于聚合聚N,N-二甲基-N,N-二烯丙基氯化铵。实验使用STATISTICA 13软件包建模。给出了通过激光衍射测定聚-N,N-二甲基-N,N-二烯丙基氯化铵样品的粒​​度的结果。通过木质素磺酸亚硫酸盐的红外光谱和纤维素生产的中性亚硫酸盐方法对官能团的组成进行了比较分析。基于木质素磺酸盐在亚硫酸盐和中性亚硫酸盐中的木质素磺酸盐的IR光谱对官能团的组成进行了比较分析。采用亚硫酸盐法生产纤维素。电位滴定法用于研究木质素磺酸盐与Fe(77)离子和基于改性木质素磺酸盐和聚N,N-二甲基-N,N-二烯丙基氯化铵的聚电解质复合物的可能络合。研究了获得的聚电解质配合物样品在苛刻温度条件下对钻井泥浆过滤性能的影响。电位滴定法用于研究木质素磺酸盐与Fe(77)离子和基于改性木质素磺酸盐和聚N,N-二甲基-N,N-二烯丙基氯化铵的聚电解质复合物的可能络合。研究了获得的聚电解质配合物样品在苛刻温度条件下对钻井泥浆过滤性能的影响。电位滴定法用于研究木质素磺酸盐与Fe(77)离子和基于改性木质素磺酸盐和聚N,N-二甲基-N,N-二烯丙基氯化铵的聚电解质复合物的可能络合。研究了获得的聚电解质配合物样品在苛刻温度条件下对钻井泥浆过滤性能的影响。

更新日期:2021-02-01
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