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Role of annealing temperature in tailoring Ce-Doped LaFeO3 features
Journal of Physics and Chemistry of Solids ( IF 4.3 ) Pub Date : 2021-01-29 , DOI: 10.1016/j.jpcs.2021.109980
M.M. Arman , S.I. El-Dek

Recently, LaFeO3 has become the focus of intense research effort because it is a room-temperature single-phase multiferroic. Here, La0.80Ce0.20FeO3 nanoparticles have been prepared as a single phase on the nanoscale by a flash combustion methodology. The powder was annealed at different temperatures to investigate the influence of the annealing temperature on the physico-chemical features. X-ray diffraction analysis of La0.80Ce0.20FeO3 samples confirmed an orthorhombic structure with the space group Pbnm. The morphologies of the samples were studied by field-emission scanning electron microscopy (FESEM). The samples have a sponge-like morphology, and the pore size decreases with increasing annealing temperature. The molar magnetic susceptibilities of the samples were measured as a function of temperature, and showed an antiferromagnetic trend. For the sample annealed at 500 °C, the value of the effective magnetic moment, μeff, decreased as the Néel temperature, TN, increased. The dielectric properties and conductivities of the samples indicated a semiconductor-like nature, with two different conduction mechanisms. The morphological features of the investigated samples suggest their potential use in gas-sensing applications, water detoxification, and Li-ion batteries.



中文翻译:

退火温度在定制Ce掺杂LaFeO 3特征中的作用

近年来,LaFeO 3是室温下的单相多铁性体,因此成为研究热点。在这里,已经通过快速燃烧方法将La 0.80 Ce 0.20 FeO 3纳米颗粒制备成纳米级的单相。将粉末在不同温度下退火以研究退火温度对理化特性的影响。La 0.80 Ce 0.20 FeO 3样品的X射线衍射分析证实了空间群为Pbnm的正交结构。通过场发射扫描电子显微镜(FESEM)研究了样品的形态。样品具有海绵状的形态,并且孔径随着退火温度的升高而减小。测量样品的摩尔磁化率随温度的变化,并显示出反铁磁趋势。对于在500°C下退火的样品,有效磁矩μeff随尼尔温度T N的升高而降低。样品的介电性能和电导率表明具有类似半导体的性质,具有两种不同的导电机理。被调查样品的形态特征表明它们在气体传感应用,水排毒和锂离子电池中的潜在用途。

更新日期:2021-02-08
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