One‐Pot Synthesis of 5‐Amino‐1,2,3‐triazole Derivatives via Dipolar Azide−Nitrile Cycloaddition and Dimroth Rearrangement under Solvent‐Free Conditions,European Journal of Organic Chemistry

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One‐Pot Synthesis of 5‐Amino‐1,2,3‐triazole Derivatives via Dipolar Azide−Nitrile Cycloaddition and Dimroth Rearrangement under Solvent‐Free Conditions
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-01-27 , DOI: 10.1002/ejoc.202001620
Pavel Gribanov ₁ , Edita M. Atoian ₂ , Anna N. Philippova ₂ , Maxim A. Topchiy ₃ , Andrey F. Asachenko ₃ , Sergey N. Osipov ₂

Affiliation

A series of novel 5‐amino‐1,2,3‐triazole derivatives has been synthesized by combining a dipolar azide−nitrile cycloaddition with a Dimroth rearrangement under solvent‐free conditions. Solvent‐free approach for the synthesis of 5‐amino‐1,2,3‐triazoles is reported for the first time.