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Study on the synthesis and optical properties of YIn1-xMnxO3 by N/S doping
Solid State Sciences ( IF 3.4 ) Pub Date : 2021-01-27 , DOI: 10.1016/j.solidstatesciences.2020.106516
Lin Liu , Moying Li , Peng Jiang , Kunyang Cui , Yuqian Wang , Jianlei Kuang , Wenbin Cao

The solid solution of YIn1-xMnxO3 shows intense blue colors as well as excellent properties. In this paper, N- and N/S- doped YIn1-xMnxO3 samples are successfully prepared by the high-energy ball milling method with hexamethylenetetramine (C6H12N4), urea (CH4N2O) and thiourea (CH4N2S). The X-ray diffraction patterns of samples with various anion doping all show single phase and the oxidation state of Mn are maintained as +3. In C6H12N4 treated YIn0.7Mn0.3O3, N is in the interstitial site while in CH4N2O treated YIn0.7Mn0.3O3, N exists in both interstitial site and substitution site. In CH4N2S treated YIn0.7Mn0.3O3, both S and N are in the substitution site and interstitial site. Due to the anion doping by N and S, the optical properties of the samples are modified and analyzed.



中文翻译:

N / S掺杂合成YIn1-xMnxO3及其光学性质的研究

YIn 1- x Mn x O 3的固溶体显示出强烈的蓝色以及优异的性能。本文采用六亚甲基四胺(C 6 H 12 N 4),尿素(CH 4 N 2 O )通过高能球磨法成功制备了N和N / S掺杂的YIn 1- x Mn x O 3样品。)和硫脲(CH 4 N 2 S)。具有各种阴离子掺杂的样品的X射线衍射图均显示为单相,并且Mn的氧化态保持为+3。在C 6 H 12中N 4处理的YIn 0.7 Mn 0.3 O 3中,N存在于间隙位置,而在CH 4 N 2 O处理的YIn 0.7 Mn 0.3 O 3中,N存在于间隙位置和置换位置。在CH 4 N 2 S处理的YIn 0.7 Mn 0.3 O 3中,S和N均位于取代位点和间隙位点。由于N和S掺杂了阴离子,因此可以修改和分析样品的光学性能。

更新日期:2021-02-03
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