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Investigation of crystal structure, dielectric response and magnetic properties of Tb3+ substituted Co2 Y-type barium hexaferrites
Solid State Sciences ( IF 3.4 ) Pub Date : 2021-01-27 , DOI: 10.1016/j.solidstatesciences.2021.106549
G. Mukhtar , J. Mohammed , Tchouank Tekou Carol T. , N. Halilu , Shaweta Sharma , U.M. Isah , Sachin Kumar Godara , A.K. Srivastava

Y-type hexaferrites powder samples of Ba1·8Sr0·2Co2Fe12-xTbxO22 (with x = 0.0, 0.1, and 0.2) were prepared by the method of sol-gel auto combustion. XRD and Rietveld refinement analysis shows that the prepared Y-type hexaferrites samples exhibit pure crystalline phase with the absence of impurity. FTIR study gives an idea of the formation of Y-type hexaferrites by the appearance of three characteristics bands at 409, 433, and 552 cm−1. FESEM analysis shows plate-like morphology with the presence of all hosts and substituted elements observed in the EDX spectra and mapping. The grain size decreases with increase in the concentration of Tb3+, the particle size was observed to be in the range 56.48–58.54 nm. Typical dielectric response of ferrites was observed in the dielectric analysis. Cole-Cole plot shows that the contribution of grain is negligible compared to grain boundaries contribution. The multi domain magnetic nature of the prepared Y-type hexaferrite samples resulted in domain wall displacement and consequently influences the values of the coercivity.



中文翻译:

Tb 3+取代的Co 2 Y型六方钡铁氧体的晶体结构,介电响应和磁性能的研究

采用溶胶-凝胶自燃法制备了Ba 1·8 Sr 0·2 Co 2 Fe 12-x Tb x O 22(x = 0.0、0.1和0.2)的Y型六价铁氧体粉末样品。XRD和Rietveld精炼分析表明,所制备的Y型六价铁氧体样品显示出纯晶相而没有杂质。FTIR研究通过在409、433和552 cm -1处出现三个特征带给出了形成Y型六铁氧体的想法。FESEM分析显示板状形态,在EDX光谱和作图中观察到所有主体和取代元素的存在。随着Tb 3+浓度的增加晶粒尺寸减小,观察到粒径在56.48–58.54 nm之间。在介电分析中观察到铁氧体的典型介电响应。Cole-Cole图显示,与晶界贡献相比,晶粒的贡献可忽略不计。制备的Y型六方铁氧体样品的多畴磁性会导致畴壁位移,从而影响矫顽力值。

更新日期:2021-02-09
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