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Synthesis of amino acid functionalized Fe 3 O 4 nanoparticles for adsorptive removal of Rhodamine B
Applied Water Science ( IF 5.7 ) Pub Date : 2021-01-28 , DOI: 10.1007/s13201-021-01371-y
Neway Belachew , Aschalew Tadesse , Mebrahtu Hagos Kahsay , Desta Shumuye Meshesha , Keloth Basavaiah

L-Aspartic acid (L-Asp) functionalized magnetite nanoparticles (Fe3O4 NPs) were synthesized through a facile co-precipitation method using L-Asp as a capping agent. UV–Vis, FTIR, XRD, SEM, EDS, TEM, and VSM techniques were used to investigate the formation, morphology, elemental composition, and magnetic properties of the synthesized Fe3O4 NPs. Highly crystalline and spherical shaped pure phase Fe3O4 NPs were successfully synthesized using amino acid as a capping agent. The magnetic measurement analysis confirms the superparamagnetic nature of the synthesized L-Asp capped Fe3O4 NPs. The adsorption efficiency of L-Asp capped Fe3O4 NPs was assessed by the removal of Rhodamine B (RhB). The optimum removal efficiency was found to be 7.7 mg g−1 using 1 mg mL−1 adsorbent, and 30 mg L−1 RhB at pH 7 and 25 °C. The regression (R2adj) and standard deviation (SD) analysis were used to validate both kinetic and isotherm models. Avrami fractional-order and Liu models were selected as the best kinetic and isotherms, respectively. The maximum adsorption capacity (Qo) of L-Asp Fe3O4 NPs toward RhB Liu’s model was found to be 10.44 mg g−1.



中文翻译:

氨基酸官能化Fe 3 O 4纳米粒子的吸附去除罗丹明B的合成

L-天冬氨酸(L-Asp)功能化的磁铁矿纳米颗粒(Fe 3 O 4 NPs)是通过使用L-Asp作为封端剂的简便共沉淀法合成的。使用紫外可见,傅立叶变换红外光谱(FTIR),X射线衍射(XRD),SEM,EDS,TEM和VSM技术研究合成的Fe 3 O 4 NP的形成,形态,元素组成和磁性。以氨基酸为封端剂成功合成了高结晶度和球形的纯相Fe 3 O 4 NP。磁测量分析证实了合成的L-Asp封端的Fe 3 O 4 NP的超顺磁性。L-Asp封端铁的吸附效率通过去除若丹明B(RhB)评估3 O 4 NP。使用1 mg mL -1吸附剂和30 mg L -1 RhB在pH 7和25°C下的最佳去除效率为7.7 mg g -1。回归分析(R 2 adj)和标准差分析(SD)用于验证动力学模型和等温线模型。Avrami分数阶模型和Liu模型分别被选为最佳动力学和等温线。发现L-Asp Fe 3 O 4 NPs对RhB Liu模型的最大吸附容量(Q o)为10.44 mg g -1

更新日期:2021-01-28
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