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Improving the energy release characteristics of PTFE/Al by doping magnesium hydride
Defence Technology ( IF 5.0 ) Pub Date : 2021-01-27 , DOI: 10.1016/j.dt.2020.12.008
Jia-xiang Wu 1 , Qiang Liu 1 , Bin Feng 2 , Qin Yin 1 , Yu-chun Li 1 , Shuang-zhang Wu 1 , Zhong-shen Yu 3 , Jun-yi Huang 1 , Xin-xin Ren 1
Affiliation  

Magnesium hydride (MgH2) was doped into PTFE/Al to improve the energy release characteristics of the material system and strive for better application in military engineering. Five types of PTFE/Al/MgH2 reactive materials with different MgH2 content were prepared by molding sintering method. The dynamic mechanical properties of the materials were studied by performing split-Hopkinson pressure bar (SHPB) tests and scanning electron microscope characterizations. The thermal behavior, reaction energy, reaction process and reaction mechanism were systematically investigated by conducting thermogravimetry-differential scanning calorimetry tests, oxygen bomb calorimeter measurements, X-ray diffraction and SHPB tests. The results show that MgH2 particles less than 10% content contribute to heightening the dynamic mechanical properties of PTFE/Al system. The product Mg generated by decomposition of MgH2 can not only react with gas phase C2F4+ but also undergo a Grignard-type reaction with condensed PTFE. The reaction energy and ignition threshold of PTFE/Al/MgH2 reactive materials enhance monotonously as MgH2 content rose. With the increase of MgH2 content from 0% to 20%, the reaction time is prolonged as well as the reaction intensity is enhanced dramatically arising from the massive water vapour produced by the reaction between O2 and H2. The gaseous products generated can form a high pressure shortly after the reaction, which helps to elevate the damage effect of the PTFE/Al system.



中文翻译:

通过掺杂氢化镁提高PTFE/Al的能量释放特性

将氢化镁(MgH 2)掺杂到PTFE/Al中,以改善材料体系的能量释放特性,争取在军事工程中得到更好的应用。采用模压烧结法制备了五种不同MgH 2含量的PTFE/Al/MgH 2反应材料。通过进行分裂霍普金森压力棒(SHPB)测试和扫描电子显微镜表征研究了材料的动态力学性能。通过热重-差示扫描量热测试、氧弹量热仪测量、X射线衍射和SHPB测试,系统地研究了热行为、反应能、反应过程和反应机理。结果表明,MgH 2小于 10% 的颗粒有助于提高 PTFE/Al 系统的动态机械性能。MgH 2分解生成的产物Mg不仅可以与气相C 2 F 4 +反应,还可以与缩合的PTFE发生格氏反应。PTFE/Al/MgH 2反应材料的反应能和着火阈值随着MgH 2含量的增加而单调增加。随着MgH 2含量从0%增加到20%,由于O 2和H 2反应产生大量水蒸气,反应时间延长,反应强度显着增强. 生成的气态产物在反应后不久会形成高压,这有助于提高 PTFE/Al 体系的破坏效果。

更新日期:2021-01-27
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