Chiral Cobalt‐Salen Complexes: Ubiquitous Species in Asymmetric Catalysis,The Chemical Record

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Chiral Cobalt‐Salen Complexes: Ubiquitous Species in Asymmetric Catalysis
The Chemical Record ( IF 7.0 ) Pub Date : 2021-01-26 , DOI: 10.1002/tcr.202000166
Emmanuelle Schulz ₁

Affiliation

Since the discovery of their extraordinary reactivity in the hydrolytic kinetic resolution of terminal epoxides about twenty years ago, chiral cobalt‐salen complexes have been shown to be essential for many other asymmetric catalytic reactions. This account summarizes the inspiring works dedicated to the discovery of their new reactivity and their mode of action, as well as the new processes towards the optimization of their cooperativity for bimetallic activation and the implementation of their effective immobilization, including also our contribution on these topics.

中文翻译：

手性钴-萨伦配合物：不对称催化中的无处不在的物种。

自大约20年前发现其在末端环氧化物的水解动力学拆分中具有非凡的反应活性以来，已显示手性钴－salen配合物对于许多其他不对称催化反应至关重要。该报告总结了一些鼓舞人心的作品，这些作品致力于发现其新的反应性及其作用方式，以及优化其双金属激活的协同性和实现其有效固定化的新过程，包括我们在这些主题上的贡献。

更新日期：2021-02-18

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