A novel PANI-derived@Al₂O₃ hybrid has been fabricated using different amounts of Al₂O₃ via the polymerization of 2-chloroaniline with ammonium persulfate as the oxidant. The resulting samples were fully characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infra-red (FT-IR) and UV–vis spectroscopy, which show that the polymerization reaction occurred. Importantly, this work provides a helpful way of setting the optical properties of resulting nanocomposites by adjusting the quantity of nanoparticles; the band gap values of poly (2ClAni)@Al₂O₃ increases upon increasing the Al₂O₃ content. This was attributed to the rearrangement that occurs in the polymer matrix upon the addition of the nanoparticles. The electrochemical properties of the resulting hybrid materials were investigated using cyclic voltammetry.

通过2-氯苯胺与过硫酸铵作为氧化剂的聚合反应，使用不同量的Al ₂ O ₃制备了一种新颖的PANI衍生的Al ₂ O ₃杂化物。所得样品通过X射线光电子能谱（XPS），X射线衍射（XRD），扫描电子显微镜（SEM）以及傅立叶变换红外光谱（FT-IR）和紫外可见光谱进行了充分表征，表明发生聚合反应。重要的是，这项工作提供了一种有用的方法，可以通过调节纳米颗粒的数量来设置所得纳米复合材料的光学性能。Al （2ClAni）@Al ₂ O ₃的带隙值随Al _2的增加而增加O ₃含量。这归因于添加纳米颗粒后聚合物基质中发生的重排。使用循环伏安法研究了所得杂化材料的电化学性能。