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Supercapacitor and room temperature H, CO2 and CH4 gas storage characteristics of commercial nanoporous activated carbon
Journal of Physics and Chemistry of Solids ( IF 4.3 ) Pub Date : 2021-01-25 , DOI: 10.1016/j.jpcs.2021.109969
A. Ramesh , M. Jeyavelan , J.A. Alex Rajju Balan , O.N. Srivastava , M. Sterlin Leo Hudson

This paper discusses the electrochemical energy storage and room temperature hydrogen, methane and carbon dioxide adsorption/desorption behaviour of commercial nanoporous activated carbon having a specific BET surface area 1007 m2 g−1 and pore volume 0.371 cm3 g−1. The electrochemical energy storage behaviour of activated carbon was determined from its capacitive performance using standard three and two-electrode cells. The specific capacitance (CS) of the sample determined using a three-electrode cell is 138 F g−1 at 0.1 A g−1 with the capacitance loss of 1% after 2000 charge/discharge cycles. Whereas, CS determined using a two-electrode cell is 98.8 F g−1 at 0.2 A g−1 with the capacitance loss of 3% after 5000 charge/discharge cycles. The energy and power densities of two-electrode cell supercapacitor is 19.76 Wh kg−1 and 3.77 kW kg−1, respectively. The sample exhibits gaseous uptake capacities of 0.23 wt% H2, 8.52 wt% CH4 and 37.25 wt% CO2 at ~50 atm/293 K.



中文翻译:

商用纳米多孔活性炭的超级电容器和室温H,CO 2 和CH 4储气特性

本文讨论了比表面积为1007 m 2  g -1和孔体积为0.371 cm 3  g -1的市售纳米多孔活性炭的电化学能量存储和室温下氢,甲烷和二氧化碳的吸附/解吸行为。使用标准的三电极和两电极电池,根据其电容性能确定活性炭的电化学储能性能。使用三电极电池确定的样品的比电容(C S)在0.1 A g -1下为138 F g -1,在2000次充电/放电循环后电容损失为1%。而C S使用两电极电池测得的0.2 A g -1下为98.8 F g -1,经过5000次充电/放电循环后电容损失为3%。双电极电池超级电容器的能量密度和功率密度分别为19.76 Wh kg -1和3.77 kW kg -1。0.23%(重量)H的样品表现出气态吸附容量2,8.52重量%的CH 4和37.25%(重量)CO 2在约50个大气压/ 293 K.

更新日期:2021-02-05
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