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Solvent assisted synthesis of hierarchical magnesium oxide flowers for adsorption of phosphate and methyl orange: Kinetic, isotherm, thermodynamic and removal mechanism
Surfaces and Interfaces ( IF 5.7 ) Pub Date : 2021-01-23 , DOI: 10.1016/j.surfin.2021.100953
Saeed Ahmed , Habib Ur Rehman , Zahid Ali , Abdul Qadeer , Abdul Haseeb , Zeeshan Ajmal

Porous flowers-like magnesium oxide (MgO) was prepared using a facile and low-cost method. The structure, morphology and pore properties of prepared MgO were investigated. The results revealed that as-prepared MgO possesses hierarchical flowers-like structural features with a large surface area of 117.48 m2 g−1. Excellent adsorption capacity, towards phosphate and methyl orange, was exhibited by the fabricated MgO having an adsorption capacity of 724 mg g−1 and 1715 mg g−1 for phosphate and methyl orange respectively. The experimental data better fitted the pseudo-second-order and Freundlich isotherm model demonstrating multilayer adsorption of pollutants onto MgO adsorbent with endothermic nature. In five consecutive adsorptions/desorption cycles, the regenerated particles retained their adsorption performance. This work provides a pathway for the large-scale development of efficient adsorbent materials to overcome the sustainable problems.



中文翻译:

溶剂辅助合成分层氧化镁花以吸附磷酸盐和甲基橙:动力学,等温线,热力学和去除机理

多孔的花状氧化镁(MgO)使用简便且低成本的方法制备。研究了制备的MgO的结构,形貌和孔隙性质。结果表明,所制备的MgO具有分层的花状结构特征,具有117.48m 2 g -1的大表面积。所制得的MgO具有724 mg g -1和1715 mg g -1的吸附能力,对磷酸盐和甲基橙表现出优异的吸附能力。分别用于磷酸盐和甲基橙。实验数据更好地拟合了伪二阶和Freundlich等温线模型,该模型证明了污染物在具有吸热特性的MgO吸附剂上的多层吸附。在五个连续的吸附/解吸循环中,再生颗粒保持了其吸附性能。这项工作为大规模开发有效的吸附材料提供了一条途径,以克服可持续性问题。

更新日期:2021-02-01
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