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Synthesis of nanocrystalline eskolaite via grimaldiite
Chemical Papers ( IF 2.1 ) Pub Date : 2020-09-03 , DOI: 10.1007/s11696-020-01338-4
Marko Robić , Mira Ristić , Stjepko Krehula , Marijana Jurić , Svetozar Musić

Grimaldiite (α-CrOOH) was precipitated hydrothermally from the CrCl3 aqueous solution in the presence of hexamethylenetetramine (HMTA). The crystallite size of grimaldiite samples was estimated to be ~ 2 nm. Eskolaite (α-Cr2O3) was produced by the calcination of grimaldiite at 500 and 700 °C. FE-SEM images showed amorphous-like aggregates of grimaldiite due to very fine particles (crystallites), whereas eskolaite was in the form of sphere-like nanoparticles. Synthesized grimaldiite and eskolaite were used in the investigation of rhodamine B (RhB) degradation. The significant degradation percentage of RhB obtained by grimaldiite was explained as catalytic effect (in dark) and photocatalytic contribution (with illumination).



中文翻译:

用格里木沸石合成纳米晶硅钙石

在六亚甲基四胺(HMTA)的存在下,从CrCl 3水溶液中水热沉淀出Grimaldiite(α-CrOOH )。Grimaldiite样品的微晶尺寸估计约为2 nm。绿铬矿(α-的Cr 2 ö 3)通过grimaldiite的在500和700℃下煅烧制成。FE-SEM图像显示出由于极细的颗粒(微晶)而形成的类似grimitiite的无定形聚集体,而eskolaite则呈球形纳米颗粒的形式。合成的格里木沸石和依考拉石用于罗丹明B(RhB)的降解研究。Grimaldiite获得的RhB的显着降解百分比可解释为催化作用(在黑暗中)和光催化作用(在光照下)。

更新日期:2020-09-03
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