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A facile synthesis of nitrogen-doped bamboo-shaped carbon nanotubes by catalytic decomposition of 2-aminopyrimidine over Fe@MgO catalyst through chemical vapor deposition method
Chemical Papers ( IF 2.2 ) Pub Date : 2020-08-28 , DOI: 10.1007/s11696-020-01333-9
Ebrahim Rezaii , Mehrdad Mahkam , Mohammad Ghaleh Assadi , Hadi Dolati

In this work, nitrogen-doped bamboo-shaped carbon nanotube (nitrogen-doped CNT) was prepared using the Chemical Vapor Deposition Method (CVD). For the first time, 2-aminopyrimidine (a carbon and nitrogen resources) was used as a precursor over Fe@MgO catalyst and employed in CVD. The prepared CNT was characterized via elemental analysis, Fourier Transform Infrared Spectroscopy (FT-IR), Energy Dispersive X-ray Spectroscopy (EDX), Transmission Electron Microscopy (TEM), X-ray Diffraction (XRD), Raman Spectroscopy and Scanning Electron Microscope (SEM). The amount of nitrogen in the prepared CNT was about 5.8%. The FT-IR spectrum reveals the presence of C–N and C = N bonds in the prepared CNT structure. The prepared CNT has bamboo-like structure with a diameter of less than 100 nm.



中文翻译:

通过化学气相沉积法在Fe @ MgO催化剂上催化2-氨基嘧啶催化分解氮掺杂竹形碳纳米管

在这项工作中,使用化学气相沉积法(CVD)制备了氮掺杂的竹形碳纳米管(氮掺杂的CNT)。首次将2-氨基嘧啶(一种碳和氮资源)用作Fe @ MgO催化剂的前体,并用于CVD。通过元素分析,傅立叶变换红外光谱(FT-IR),能量色散X射线光谱(EDX),透射电子显微镜(TEM),X射线衍射(XRD),拉曼光谱和扫描电子显微镜对制备的CNT进行表征(SEM)。制备的CNT中的氮量为约5.8%。FT-IR光谱揭示了所制备的CNT结构中存在C–N和C = N键。制备的CNT具有直径小于100nm的竹状结构。

更新日期:2020-08-28
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