An analysis of electrophilic aromatic substitution: a “complex approach”,Physical Chemistry Chemical Physics

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An analysis of electrophilic aromatic substitution: a “complex approach”
Physical Chemistry Chemical Physics ( IF 2.9 ) Pub Date : 2021-1-7 , DOI: 10.1039/d0cp05245k
Nikola Stamenković _{1,

2,

3,

4} , Nataša Poklar Ulrih _{1,

2,

3,

4} , Janez Cerkovnik _{3,

4,

5,

6,

7}

Affiliation

Electrophilic aromatic substitution (EAS) is one of the most widely researched transforms in synthetic organic chemistry. Numerous studies have been carried out to provide an understanding of the nature of its reactivity pattern. There is now a need for a concise and general, but detailed and up-to-date, overview. The basic principles behind EAS are essential to our understanding of what the mechanisms underlying EAS are. To date, textbook overviews of EAS have provided little information about the mechanistic pathways and chemical species involved. In this review, the aim is to gather and present the up-to-date information relating to reactivity in EAS, with the implication that some of the key concepts will be discussed in a scientifically concise manner. In addition, the information presented herein suggests certain new possibilities to advance EAS theory, with particular emphasis on the role of modern instrumental and theoretical techniques in EAS reactivity monitoring.

中文翻译：

亲电芳香族取代分析：“复杂方法”

亲电子芳族取代（EAS）是合成有机化学中研究最广泛的转化之一。已经进行了许多研究以提供对其反应模式性质的理解。现在需要一个简明，通用但又详尽而又最新的概述。EAS背后的基本原则对于我们了解EAS的基本机制至关重要。迄今为止，有关EAS的教科书概述几乎没有提供有关所涉及的机械途径和化学物质的信息。在这篇综述中，目的是收集和介绍与EAS中反应性有关的最新信息，这意味着某些关键概念将以科学简洁的方式进行讨论。此外，

更新日期：2021-01-22

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