The phase diagram of the Cu₂CdSnS₄–Cu₂ZnSnS₄system was constructed using data on differential thermal, X-ray phase and microstructure analysis methods. The diagram can be attributed to the first type according to the Rosebohm classification. The Cu₂CdSnS₄–Cu₂ZnSnS₄ solid solution single crystals were grown by chemical vapor transport using iodine as a transport agent. Their structure and unit cell parameters as well as compositional dependences of lattice parameters, pycnometric, X-ray densities and microhardness were determined. It was found that the Vegard's law is fulfilled in solutions studied.

中文翻译：

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Cu ₂ Cd _1-x Zn _x SnS ₄固溶体的生长，晶体结构和性能

利用关于差热，X射线相和微观结构分析方法的数据，构建了Cu ₂ CdSnS ₄ –Cu ₂ ZnSnS ₄体系的相图。该图可以根据Rosebohm分类归因于第一类。Cu ₂ CdSnS ₄ –Cu ₂ ZnSnS ₄固溶单晶是通过使用碘作为传输剂的化学气相传输来生长的。确定了它们的结构和晶胞参数，以及晶格参数，比重，X射线密度和显微硬度的成分依赖性。发现在所研究的解中满足了维加德定律。