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Improved stabilization of coix seed oil in a nanocage-coating framework based on gliadin-carboxymethyl chitosan-Ca2+
Carbohydrate Polymers ( IF 11.2 ) Pub Date : 2021-01-21 , DOI: 10.1016/j.carbpol.2020.117557
Wenyu Zheng , Zhan-peng Chen , Yan-Hong Yang , Rong Yang , Tu-di Yang , Pei-Li Lai , Tong-lin Chen , Shui-ling Qiu , Shao-yun Wang , Lan Liao

Coix seed oil (CSO) is easily suffered functional-loss by oxidation and hydrothermal-treatment. The environmental stable nanocage-coating-CSO particles (OGC-Ca) by the frameworks consist of gliadins, carboxymethyl chitosan (CMCS) and Ca2+ were investigated. Results showed Ca2+ was the key controller for fabricating this nanocage-coating-frameworks, bridging macromolecule-chains with electrostatic interaction and hydrogen bonds, detected by FTIR, CD, DSC and XRD. SEM displayed new-formed velvet-like twigs after cross-linking CMCS to gliadins. Ca2+ assisted the nanocage-coating by significant down-sizing conversion OGC to OGC-Ca with consumption of twigs. OGC-Ca displayed a good stability towards heat (60−80 °C, 0−80 min), pH (3–8), NaCl (0−0.5 mM), storage (4/25 °C, 12 days), and a reduce of the pre-oxidation value of CSO in water and the improved controlled release of CSO in simulated GI tract. It illustrated GC-Ca frameworks would be a suitable delivery carrier for the CSO like pharmaceuticals and nutraceuticals for the food or medical use.



中文翻译:

在基于麦醇溶蛋白-羧甲基壳聚糖-Ca 2+的纳米笼涂层框架中改善仁油的稳定性

oxidation仁油(CSO)容易受到氧化和水热处理的功能损失。研究了由麦醇溶蛋白,羧甲基壳聚糖(CMCS)和Ca 2+组成的骨架结构的环境稳定的纳米笼涂层CSO颗粒(OGC-Ca)。结果表明,Ca 2+是制造该纳米笼涂层框架的关键控制因素,通过FTIR,CD,DSC和XRD检测,该桥将具有静电相互作用和氢键的大分子链桥接。在将CMCS交联至麦醇溶蛋白后,SEM展示了新型的天鹅绒状细枝。钙2+通过消耗大量细枝,将OGC尺寸大幅缩小为OGC-Ca,有助于纳米笼涂层。OGC-Ca对热(60-80°C,0-80分钟),pH(3-8),NaCl(0-0.5 mM),储存(4/25°C,12天)和降低了水中CSO的预氧化值,并改善了模拟胃肠道中CSO的控制释放。它说明了GC-Ca框架将是适合CSO的传递载体,例如用于食品或医疗用途的药品和保健食品。

更新日期:2021-01-22
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