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Catalytic flash pyrolysis of Monoraphidium sp. before and after lipid extraction
Algal Research ( IF 4.6 ) Pub Date : 2021-01-21 , DOI: 10.1016/j.algal.2021.102199
Thalita M. Delmiro , Rebecca R.Y.O.V. Wilson , Dulce M.A. Melo , Graco A.C.M. Viana , Leonardo B.B. Mendes , Renata M. Braga

The use of biomass from Monoraphidium sp. microalgae before and after lipid extraction was investigated using flash catalytic pyrolysis to generate a bio-oil with improved characteristics. The biomass was obtained from intensive outdoor crops and exhibited an attractive biochemical composition to be used in thermochemical processes with high protein and carbohydrate content remaining after lipid extraction. Flash pyrolysis of biomass before and after extraction was developed at 500 °C in an analytical micro-pyrolyzer coupled to a gas chromatography/mass spectrometry (Py-GC/MS) instrument and the pyrolysis vapors were transported to a catalytic bed at 300 °C. Pyrolysis vapors were improved in the catalytic pyrolysis using zeolite HZSM-5 which promoted the deoxygenation and complete denitrogenation of the products. Furthermore, the formation of aromatics in the biomass was increased before and after extraction to 87.45% and 95.08%, respectively, thus demonstrating the potential of this process to generate a high quality bio-oil which can be used in several applications in chemical and fuel industries.



中文翻译:

Monoraphidium sp。的催化快速热解。脂质提取前后

独栖生物的生物质利用sp。使用快速催化热解法研究脂质提取前后的微藻,以产生具有改善特性的生物油。生物质是从集约化的室外农作物中获得的,并表现出有吸引力的生化成分,可用于热化学过程,脂质提取后残留的蛋白质和碳水化合物含量高。在与气相色谱/质谱(Py-GC / MS)仪器耦合的分析型微型热解器中,在提取前和提取后的生物质进行快速热解在500°C下进行,并将热解蒸气在300°C下输送到催化床中。使用沸石HZSM-5改善了催化热解过程中的热解蒸气,该沸石可促进产物的脱氧和完全脱氮。此外,

更新日期:2021-01-22
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