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o-Quinone Methides and o-Quinone Sulfides via Arynes: Synthesis of Ortho-Disubstituted Arenes and Heterocycles
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2021-01-20 , DOI: 10.1021/acs.joc.0c02908 Abhilash Sharma 1, 2 , Hemanta Hazarika 1, 2 , Pranjal Gogoi 1, 2
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2021-01-20 , DOI: 10.1021/acs.joc.0c02908 Abhilash Sharma 1, 2 , Hemanta Hazarika 1, 2 , Pranjal Gogoi 1, 2
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In recent decades, o-quinone methides and o-quinone sulfides have been extensively highlighted as reactive intermediates for the synthesis of diversely functionalized ortho-disubstituted arenes and heterocycles. Additionally, ortho-disubstituted arenes offer a constructive path for the synthesis of fused carbocycles, heterocycles, natural products, and drug candidates. In the lieu of that, this Synopsis highlights a comprehensive overview on the potential applications of in situ generated o-quinone methides and o-quinone sulfides for one-pot synthesis of ortho-disubstituted arenes and heterocycles via arynes.
中文翻译：
邻醌甲基化物和邻醌硫化物通过芳烃：邻二取代芳烃和杂环化合物的合成
近几十年来，邻醌甲基化物和邻醌硫化物作为合成多种官能化邻位二取代芳烃和杂环的反应性中间体得到了广泛关注。此外，邻二取代芳烃为稠合碳环、杂环、天然产物和候选药物的合成提供了建设性途径。取而代之的是，本概要全面概述了原位生成的邻醌甲基化物和邻醌硫化物在通过一锅法合成邻位二取代芳烃和杂环的潜在应用芳烃。
更新日期：2021-01-20
中文翻译：
邻醌甲基化物和邻醌硫化物通过芳烃：邻二取代芳烃和杂环化合物的合成
近几十年来，邻醌甲基化物和邻醌硫化物作为合成多种官能化邻位二取代芳烃和杂环的反应性中间体得到了广泛关注。此外，邻二取代芳烃为稠合碳环、杂环、天然产物和候选药物的合成提供了建设性途径。取而代之的是，本概要全面概述了原位生成的邻醌甲基化物和邻醌硫化物在通过一锅法合成邻位二取代芳烃和杂环的潜在应用芳烃。
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