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Strategies in Metal–Organic Framework‐based Catalysts for the Aerobic Oxidation of Alcohols and Recent Progress
Bulletin of the Korean Chemical Society ( IF 2.3 ) Pub Date : 2021-01-20 , DOI: 10.1002/bkcs.12197
Jooyeon Lee 1 , Seungpyo Hong 1 , Jonghyeon Lee 1 , Seongwoo Kim 2 , Jinho Kim 3 , Min Kim 1
Affiliation  

Metal–organic frameworks (MOFs), which are porous inorganic–organic hybrid materials, act as versatile catalyst platforms for various organic transformations. In particular, the aerobic oxidation of alcohols to the corresponding aldehydes (or ketones) has been extensively studied using various MOFs and their analogs. In this account, we summarize the performance of MOF‐based catalysts for the aerobic oxidation of alcohols based on the position of the catalytic species and the type of functionalization. Moreover, recent advances in MOF‐based catalysts for aerobic oxidation are discussed in terms of catalytic efficiency and substrate size discrimination.

中文翻译:

金属有机框架的酒精好氧氧化催化剂的策略和最新进展

金属-有机骨架(MOF)是多孔的无机-有机杂化材料,可作为多种有机转化的多功能催化剂平台。特别地,已经使用各种MOF及其类似物对醇有氧氧化为相应的醛(或酮)进行了广泛的研究。在此说明中,我们根据催化物质的位置和官能化的类型,总结了基于MOF的催化剂对酒精进行好氧氧化的性能。此外,就催化效率和底物尺寸区分而言,讨论了基于MOF的好氧氧化催化剂的最新进展。
更新日期:2021-03-18
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