Synthesis of (±)‐epi‐Jungianol by the Gold(I)‐Catalyzed Propargyl Claisen Rearrangement/Hydroarylation Cascade Reaction of Propargyl Vinyl Ethers,European Journal of Organic Chemistry

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Synthesis of (±)‐epi‐Jungianol by the Gold(I)‐Catalyzed Propargyl Claisen Rearrangement/Hydroarylation Cascade Reaction of Propargyl Vinyl Ethers
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-01-21 , DOI: 10.1002/ejoc.202001555
Antonia Rinaldi ₁ , Vittoria Langé ₁ , Dina Scarpi ₁ , Ernesto Giovanni Occhiato ₂

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The total synthesis of epi‐jungianol was carried out by exploiting the gold(I)‐catalyzed propargyl Claisen rearrangement/hydroarylation cascade reaction of substituted propargyl vinyl ethers. The methodology appears suitable for the preparation of natural and bioactive compounds containing the cis 1,3‐disubstituted indane skeleton.

中文翻译：

金（I）催化的炔丙基乙烯基醚的炔丙基克莱森重排/加氢芳基化级联反应合成（±）-表-己醇

的总合成外延-jungianol是通过利用金（I） -催化的炔丙基Claisen重排/ hydroarylation级联取代炔丙基乙烯基醚反应来进行。该方法似乎适合制备含有顺式1,3-二取代的茚满骨架的天然和生物活性化合物。

更新日期：2021-02-24

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