An electrochemical perspective on the roles of ligands in the merger of transition-metal catalysis and electrochemistry,Organic Chemistry Frontiers

当前位置： X-MOL 学术 › Org. Chem. Front. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

An electrochemical perspective on the roles of ligands in the merger of transition-metal catalysis and electrochemistry
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-12-28 , DOI: 10.1039/d0qo01227k
Jun-Song Zhong _{1,

2,

3,

4,

5} , Yi Yu _{1,

2,

3,

4,

5} , Zhaojiang Shi _{1,

2,

3,

4,

5} , Ke-Yin Ye _{1,

2,

3,

4,

5}

Affiliation

The merger of transition-metal catalysis and electrochemistry has emerged as a very versatile and robust synthetic tool in organic synthesis. Like in their non-electrochemical variants, ligands also play crucial roles in fundamental reactions in transition-metal catalysis under electrochemical conditions. Herein, a perspective on the roles of ligands in transition-metal catalysis under electrochemical conditions is provided with selected transformations enabled by such a merger including C–H functionalization, difunctionalization of alkenes, cross-coupling reactions and carboxylation with CO₂.

中文翻译：

过渡金属催化与电化学结合中配体作用的电化学角度

过渡金属催化与电化学的结合已成为有机合成中一种非常通用且功能强大的合成工具。与其非电化学变体一样，配体在电化学条件下的过渡金属催化中的基本反应中也起着关键作用。在本文中，对配体在电化学条件下过渡金属催化中的作用进行了展望，并提供了通过此类合并实现的选定转化，这些合并包括C–H官能化，烯烃的双官能化，交叉偶联反应以及与CO _2的羧基化。

更新日期：2021-01-20

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11