Recent Trends and Prospects in Homogeneous Manganese‐Catalysed Epoxidation,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Recent Trends and Prospects in Homogeneous Manganese‐Catalysed Epoxidation
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-01-20 , DOI: 10.1002/adsc.202001073
Rose Mary Philip ₁ , Sankaran Radhika ₁ , C. M. Afsina Abdulla ₁ , Gopinathan Anilkumar _{1,

2,

3}

Affiliation

Epoxidation of alkenes is a significant reaction in organic chemistry due to its opportunities in producing compounds of biochemical interest. Catalytic epoxidation with first‐row transition elements has gained attention in the latest years wherein manganese based catalysts stand superior by satisfying numerous principles of green chemistry. In this review, we have summarized the recent developments in olefin epoxidation using homogeneous manganese catalysts. Manganese complexes with porphyrin, Schiff base, salen, and other non‐heme ligands made efficient catalytic systems during the last five years. Notably, we witnessed greener approaches in recent reports wherein photo‐catalysis is a promising strategy. We anticipate that the review will benefit the researchers to get a better understanding of the reaction and to choose the best catalysts for their reactions.

中文翻译：

均相锰催化环氧化的最新趋势和前景

烯烃的环氧化是有机化学中的重要反应，因为它有机会生产具有生化意义的化合物。近年来，具有首行过渡元素的催化环氧化反应受到关注，其中锰基催化剂通过满足众多绿色化学原理而表现出优异的表现。在这篇综述中，我们总结了使用均相锰催化剂进行烯烃环氧化的最新进展。在过去的五年中，锰与卟啉，席夫碱，塞伦和其他非血红素配体的络合物成为有效的催化体系。值得注意的是，我们在最近的报告中目睹了更绿色的方法，其中光催化是一种有前途的策略。

更新日期：2021-03-03

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11