The palladium catalyzed telomerization of butadiene with glycerol has been efficiently performed with bubbling butadiene at atmospheric pressure leading to high selectivities into monooctadienyl glycerylethers. The catalytic activity is found to be stable for a long period of time, up to 5 days, giving rise to turnover numbers as high as 1000. The reaction has been extended to isosorbide and solketal with always selective production of the monotelomers over long time.

中文翻译：

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大气压起泡丁二烯对钯的生物基多元醇的端粒催化作用

用丁二烯在大气压下鼓泡丁二烯可有效地进行钯催化的丁二烯与甘油的端粒化，从而导致高选择性地转化为单辛二烯基甘油醚。发现催化活性在长达5天的长时间内保持稳定，从而产生高达1000的周转率。反应一直扩展到异山梨醇和Solketal，并在很长时间内始终选择性地生产单端粒。