Valence states of cyclotron-produced thallium,New Journal of Chemistry

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Valence states of cyclotron-produced thallium
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2021-1-11 , DOI: 10.1039/d0nj05198e
Evgeny E. Tereshatov _{1,

2,

3,

4} , Miroslava Semelová _{5,

6,

7,

8,

9} , Kateřina Čubová _{5,

6,

7,

8,

9} , Pavel Bartl _{5,

6,

7,

8,

9} , Mojmír Němec _{5,

6,

7,

8,

9} , Jan Štursa _{9,

10,

11,

12} , Václav Zach _{9,

10,

11,

12} , Charles M. Folden _{1,

2,

3,

4,

13} , Jon Petter Omtvedt _{13,

14,

15,

16} , Jan John _{5,

6,

7,

8,

9}

Affiliation

Unexpected behavior of thallium atoms, produced in a reaction of gold target with accelerated ³He ions, in liquid–liquid extraction with [C_nmim][NTf₂] ionic liquids (n = 2, 4, 6–8, 10) was investigated. Contrary to the general expectations, a significant proportion of thallium produced in the nuclear reaction was found in a non-monovalent state upon dissolution of the KCl aerosol collector. This finding is critical for the design and evaluation of the forthcoming chemistry experiments with the superheavy element nihonium.

中文翻译：

回旋加速器产生的al的价态

用[C _n mim] [NTf ₂ ]离子液体（n = 2、4、6–8、10）进行液-液萃取时，金靶与加速的³ He离子反应生成的al原子的异常行为为调查。与一般预期相反，在KCl气溶胶捕集剂溶解后，在核反应中产生的proportion中有很大一部分处于非单价状态。这一发现对于即将进行的超重元素镍化学实验的设计和评估至关重要。

更新日期：2021-01-19

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