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Palladium-catalyzed selective B(3)–H arylation of o-carboranes with arylboronic acids at room temperature
Chemical Communications ( IF 4.3 ) Pub Date : 2021-1-12 , DOI: 10.1039/d0cc07591d Ziyi Yang 1, 2, 3, 4, 5 , Yuanbo Wu 1, 2, 3, 4, 5 , Yatong Fu 1, 2, 3, 4, 5 , Jianxin Yang 1, 2, 3, 4, 5 , Jian Lu 5, 6, 7, 8 , Ju-You Lu 1, 2, 3, 4, 5
Chemical Communications ( IF 4.3 ) Pub Date : 2021-1-12 , DOI: 10.1039/d0cc07591d Ziyi Yang 1, 2, 3, 4, 5 , Yuanbo Wu 1, 2, 3, 4, 5 , Yatong Fu 1, 2, 3, 4, 5 , Jianxin Yang 1, 2, 3, 4, 5 , Jian Lu 5, 6, 7, 8 , Ju-You Lu 1, 2, 3, 4, 5
Affiliation
A palladium-catalyzed selective B(3)–H arylation of o-carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl-o-carboranes were obtained in good to excellent yields. This method provides a powerful synthetic route for constructing polysubstituted o-carborane derivatives.
中文翻译:
室温下钯催化邻氨基甲酸酯与芳基硼酸的选择性B(3)–H芳基化
使用容易获得的芳基硼酸作为芳基来源,开发了室温下钯催化的邻氨基甲酸酯的选择性B(3)–H芳基化反应,并以良好的收率获得了相应的3-芳基-邻氨基甲酸酯。该方法为构建多取代的邻-碳硼烷衍生物提供了有力的合成途径。
更新日期:2021-01-19
中文翻译:
室温下钯催化邻氨基甲酸酯与芳基硼酸的选择性B(3)–H芳基化
使用容易获得的芳基硼酸作为芳基来源,开发了室温下钯催化的邻氨基甲酸酯的选择性B(3)–H芳基化反应,并以良好的收率获得了相应的3-芳基-邻氨基甲酸酯。该方法为构建多取代的邻-碳硼烷衍生物提供了有力的合成途径。