We report the preliminary results of an investigation comprising of the synthesis of 1‐naphthol‐based unsymmetrical triarylmethanes via the Pd‐catalyzed Heck‐type desulfitative reaction and conjugate addition of arylsulfonyl chlorides with tetralone‐derived chalcones. Unsymmetrical triarylmethanes are valuable molecules in organic‐, medicinal and materials chemistry. This work is a contribution towards enriching the library of unsymmetrical triarylmethanes.

中文翻译：

---

基于1-萘酚的不对称三芳基甲烷的合成：芳基磺酰氯与四氢萘酮产生的Heck型脱硫反应

我们报告了一项初步研究结果，该研究包括通过Pd催化的Heck型脱硫反应和芳基磺酰氯与四氢萘酮衍生的查耳酮的共轭加成，合成基于1-萘酚的不对称三芳基甲烷。不对称的三芳基甲烷在有机化学，药物化学和材料化学中是有价值的分子。这项工作有助于丰富不对称三芳基甲烷的文库。