当前位置: X-MOL 学术J. Mater. Process. Tech. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Effect of cooling rate on fluidity and glass-forming ability of Zr-based amorphous alloys using different molds
Journal of Materials Processing Technology ( IF 6.7 ) Pub Date : 2021-01-19 , DOI: 10.1016/j.jmatprotec.2021.117051
Feilong Wang , Dawei Yin , Jingwang Lv , Shan Zhang , Mingzhen Ma , Xinyu Zhang , Riping Liu

Herein, the effect of cooling rate on fluidity and glass-forming ability (GFA) of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 amorphous alloy is systematically studied by using a self-designed fluidity testing system and gravity casting. The molds are made of refractory steel, purity graphite and copper with spiral cavities. Moreover, the fluidity model of amorphous alloy is established and flow length is calculated based on the heat balance theory. Furthermore, the fluidity of amorphous alloy melt is quantitatively and qualitatively analyzed by comparing the calculated and experimentally measured flow lengths. The results reveal that the cooling capacity of mold mainly influences the flow length of amorphous alloy melt. Moreover, the discrepancy between experimentally measured and theoretically calculated flow lengths can be ascribed to the difference between actual and theoretical thermophysical parameters. X-ray diffraction (XRD), differential scanning calorimetry (DSC) and high-resolution transmission electron microscopy (HRTEM) reveal the traces of crystalline phase in samples prepared using steel and graphite molds, however, the crystalline phase is not observed in the case of copper mold. The results demonstrate that the mold material renders a certain influence on GFA of Zr41.2Ti13.8Cu12.5Ni10Be22.5 amorphous alloy.



中文翻译:

冷却速度对不同模具Zr基非晶合金流动性和玻璃形成能力的影响

此处,冷却速度对Zr 41.2 Ti 13.8 Cu 12.5 Ni 10 Be 22.5的流动性和玻璃形成能力(GFA)的影响通过使用自行设计的流动性测试系统和重力铸造系统对非晶态合金进行了系统研究。模具由耐火钢,纯石墨和带有螺旋型腔的铜制成。此外,基于热平衡理论,建立了非晶态合金的流动性模型并计算了流动长度。此外,非晶态合金熔体的流动性通过比较计算出的流动长度和实验测量的流动长度进行定量和定性分析。结果表明,模具的冷却能力主要影响非晶态合金熔体的流动长度。此外,实验测得的流量与理论计算出的流量长度之间的差异可以归因于实际热物理参数与理论热物理参数之间的差异。X射线衍射(XRD)差示扫描量热法(DSC)和高分辨率透射电子显微镜(HRTEM)揭示了使用钢和石墨模具制备的样品中的晶相痕迹,但是,在铜模具中未观察到晶相。结果表明,模具材料对Zr的GFA有一定影响。41.2 Ti 13.8 Cu 12.5 Ni 10 Be 22.5非晶态合金。

更新日期:2021-01-28
down
wechat
bug