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Formation of hierarchical Si 3 N 4 foams by protein-based gelcasting and chemical vapor infiltration
Journal of Advanced Ceramics ( IF 18.6 ) Pub Date : 2021-01-18 , DOI: 10.1007/s40145-020-0431-4
Junsheng Li , Qiuping Yu , Duan Li , Liang Zeng , Shitao Gao

Silicon nitride foams with a hierarchical porous structure was formed by the combination of protein-based gelcasting, chemical vapor infiltration, and in-situ growth of silicon nitride nanowires. The porosity of the foams can be controlled at 76.3–83.8 vol% with an open porosity of 70.2– 82.8 vol%. The pore size distribution was presented in three levels: < 2 μm (voids among grains and cross overlapping of silicon nitride nanowires (SNNWs)), 10–50 μm (cell windows), and >100 μm (cells). The resulted compressive strength of the porous bodies at room temperature can achieve up to 18.0±1.0 MPa (porosity = 76.3 vol%) while the corresponding retention rate at 800 ℃ was 58.3%. Gas permeability value was measured to be 5.16 (cm3·cm)/(cm2·s·kPa). The good strength, high permeability together with the pore structure in multiple scales enabled the foam materials for microparticle infiltration applications.



中文翻译:

通过蛋白质基凝胶浇铸和化学气相渗透形成分层的Si 3 N 4泡沫

通过基于蛋白质的凝胶浇铸,化学气相渗透和氮化硅纳米线的原位生长相结合,形成了具有分层多孔结构的氮化硅泡沫。泡沫的孔隙率可以控制在76.3-83.8体积%,开放孔隙率为70.2-82.8体积%。孔径分布分为三个级别:<2μm(晶粒间的空隙和氮化硅纳米线(SNNWs)的交叉重叠),10–50μm(孔窗口)和> 100μm(孔)。所得的多孔体在室温下的抗压强度可达到18.0±1.0 MPa(孔隙率= 76.3 vol%),而在800℃下的相应保留率为58.3%。测得的气体渗透率值为5.16(cm 3 ·cm)/(cm 2·s·kPa)。良好的强度,高渗透性以及多种尺度的孔结构使泡沫材料可用于微粒渗透应用。

更新日期:2021-01-18
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