Front Cover Picture: Benzyl Palladium Intermediates: Unique and Versatile Reactive Intermediates for Aromatic Functionalization (Adv. Synth. Catal. 3/2021),Advanced Synthesis & Catalysis

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Front Cover Picture: Benzyl Palladium Intermediates: Unique and Versatile Reactive Intermediates for Aromatic Functionalization (Adv. Synth. Catal. 3/2021)
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-01-14 , DOI: 10.1002/adsc.202001609
Sheng Zhang ₁ , Yoshinori Yamamoto _{1,

2,

3} , Ming Bao ₁

Affiliation

The front cover picture illustrates recent advances on selective dearomatization and functionalization of aromatic rings via η³‐benzyl palladium intermediates. The importance of this topic relies on providing efficient strategy for dearomatization and functionalization of arenes and heteroarenes in mild conditions. A series of C−C or C‐heteroatom bond formation reactions is summarized. Theoretical calculations are also introduced in details, accounting for the reactions occurring regioselectively in the benzene ring, rather than benzylic position. Details can be found in the review by Ming Bao and co‐workers (S. Zhang, Y. Yamamoto, M. Bao, Adv. Synth. Catal. 2021, 363, 587–601; DOI: 10.1002/adsc.202000838).

中文翻译：

封面图片：苄基钯中间体：用于芳族官能化的独特而多功能的反应中间体（高级合成，目录号3/2021）

前盖图片示出了经由在选择性脱芳构化和芳环的官能化的最新进展η ³ -苄基钯中间体。该主题的重要性取决于在温和条件下为芳烃和杂芳烃的脱芳香化和功能化提供有效的策略。总结了一系列的CC或C-杂原子键形成反应。还详细介绍了理论计算，考虑了在苯环中而不是苄基位置上区域选择性发生的反应。细节可以在由明报和同事的审查中找到（S.章，Y.山本，M.宝，。。进阶Synth的CATAL。2021，363，587-601; DOI：10.1002 / adsc.202000838）。

更新日期：2021-02-02

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