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Effect of monovalent and divalent ion solutions as washing agents on the removal of Sr and Cs from soil near a nuclear power plant
Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2021-01-16 , DOI: 10.1016/j.jhazmat.2021.125165
Hojae Song , Hyeonyong Chung , Kyoungphile Nam

Solutions of monovalent and divalent ions, including calcium, magnesium, ammonium, and potassium, were tested in the removal of Sr and Cs from soil near a nuclear power plant. The Ca2+ and K+ solutions exhibited removal efficiencies of 68.2% and 81.3% for Sr and Cs, respectively. This high performance was probably due to the physicochemical similarities between ‘Ca and Sr’ and ‘K and Cs’. Alternatively, the Mg2+ and NH4+ solutions performed much worse, despite having the same valences as Ca2+ and K+, respectively. Ca2+ and K+ solutions could also simultaneously remove cationic toxic metals present with the nuclides, albeit much less efficiently (30–40%). For anionic metalloid As and anionic toxic metal Cr, the efficiency was even lower (< 20%). The five-step sequential extraction experiment confirmed that all chemical forms of Sr and Cs, except the residual form, were extensively removed by the Ca2+ and K+ solutions, respectively. For comparison, widely used washing agents exhibited removal efficiencies of 25–30%. Notably, Fe2+ and Mn2+ ions were hardly detected in the Ca2+ solution, while their concentrations were much higher in the common washing agents, suggesting the involvement of an ion-exchange mechanism in Sr and Cs removal, rather than a Fe/Mn oxide dissolution mechanism.



中文翻译:

一价和二价离子溶液作为清洗剂对核电站附近土壤中Sr和Cs去除的影响

测试了一价和二价离子(包括钙,镁,铵和钾)溶液在核电站附近土壤中去除Sr和Cs的能力。Ca 2+和K +溶液对Sr和Cs的去除效率分别为68.2%和81.3%。如此高的性能可能是由于“ Ca和Sr”与“ K和Cs”之间的物理化学相似性。另外,尽管Mg 2+和NH 4 +的化合价分别与Ca 2+和K +的化合价相同,但它们的性能要差得多。Ca 2+和K +溶液也可以同时去除与核素一起存在的阳离子有毒金属,尽管效率要低得多(30–40%)。对于阴离子准金属As和阴离子有毒金属Cr,效率甚至更低(<20%)。五步连续提取实验证实,锶和铯的所有化学形式,除了残留的形式,进行了广泛的由CA除去2+和K +溶液分别。为了进行比较,广泛使用的清洗剂的去除效率为25%至30%。值得注意的是,在Ca 2+中几乎未检测到Fe 2+和Mn 2+离子。 溶液,而它们在普通清洗剂中的浓度要高得多,这表明离子交换机制参与了Sr和Cs的去除,而不是Fe / Mn氧化物的溶解机制。

更新日期:2021-02-02
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