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NiO‐MnO2/Nb2O5‐TiO2 catalyzed reaction integration of butanal self‐condensation and successive hydrogenation and its kinetics
Journal of Chemical Technology and Biotechnology ( IF 2.8 ) Pub Date : 2021-01-17 , DOI: 10.1002/jctb.6671
Sibo Li 1 , Jiaxun Zhang 1 , Hualiang An 1 , Guirong Wang 1 , Xinqiang Zhao 1 , Yanji Wang 1
Affiliation  

The reaction integration of butanal self‐condensation and successive hydrogenation (that is, one‐step synthesis of 2‐ethylhexanol from butanal) is an efficiency way to simply process flow and reduce energy consumption for the commercial manufacture of 2‐ethylhexanol (2EHO). In the present work, a NiO‐MnO2/Nb2O5‐TiO2 catalyst was prepared for the integration reaction to reach a high 2‐ethylhexanol selectivity. Furthermore, the reaction integration was investigated kinetically for the next scale‐up.

中文翻译:

NiO-MnO2 / Nb2O5-TiO2催化丁醛自缩和连续加氢反应的动力学及其动力学

丁醛自缩合反应和连续氢化反应的整合(即从丁醛一步合成2-乙基己醇)是一种简单的工艺流程,可降低商业生产2-乙基己醇(2EHO)的能耗。在目前的工作中,制备了NiO-MnO 2 / Nb 2 O 5 -TiO 2催化剂用于积分反应,以达到较高的2-乙基己醇选择性。此外,为进一步扩大规模,还对动力学反应进行了动力学研究。
更新日期:2021-01-17
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