Polystyrene-b-poly(acrylic acid) (PS₅₇-b-PAA₅₄) is prepared by the Atom Transfer Radical Polymerization (ATRP), and poly(o-phenylenediamine) (PoPD) and its carbon dots composites (CDs/PoPD) are synthesized by using the self-assembled micelles of PS₅₇-b-PAA₅₄ as template. Rod-shaped PoPD and CDs/PoPD particles are formed with the average diameters of 263 nm and 322 nm, respectively. The PoPD exhibit a wide size distribution and diverse morphologies, while the CDs/PoPD is mostly composed of olive-shaped particles with a narrow size distribution. The PS₅₇-b-PAA₅₄ induced morphological formation mechanism of PoPD and CDs/PoPD is then proposed. The electrochemical performances test characterized by cyclic voltammetry, chronopotential, AC impedance and constant current charge-discharge tests in a three-electrode system reveals that the initial specific discharge capacitances of CDs/PoPD and PoPD can reach up to 1316 F·g⁻¹ and 216 F·g⁻¹, respectively, at the current density of 1 A·g⁻¹. CDs/PoPD shows better cycle stability with the specific discharge capacitance of 830 F·g⁻¹ for the first cycle, and the decline to 357 F·g⁻¹ in 2000 cycles at the current density of 1 A·g⁻¹ within the potential window of −0.2–1.4 V.

聚苯乙烯-b-聚丙烯酸（PS ₅₇ - b -PAA ₅₄）是通过原子转移自由基聚合（ATRP）和聚（邻苯二胺）（P o PD）及其碳点复合物（CDs / P ø PD）通过使用PS的自组装胶束合成₅₇ - b -PAA ₅₄作为模板。形成棒状的P o PD和CDs / P o PD颗粒，其平均直径分别为263 nm和322 nm。P o PD表现出较大的尺寸分布和多种形态，而CD / P oPD主要由粒径分布较窄的橄榄形颗粒组成。然后提出了PS ₅₇ - b -PAA ₅₄诱导的P o PD和CDs / P o PD的形态形成机制。在三电极系统中通过循环伏安法，时序电势，交流阻抗和恒流充放电测试表征的电化学性能测试表明，CDs / P o PD和P o PD的初始比放电电容可以达到1316 F·。克^-1和216·F·^克-1，分别在1个A的电流密度·^克-1。光盘/ P ØPD显示出更好的循环稳定性，第一个循环的比放电电容为830 F·g ^-1，在电势窗口内电流密度为1 A·g ^{-1的情况下}，在2000个循环中下降到357 F·g ^-1为-0.2–1.4V。