Separated pure-quadrupole (PQ) and -shift (PS) spectra of ²H nuclear magnetic resonance (NMR) of paramagnetic solids are obtained and correlated by simple pulse sequences that can acquire the full magnetization under ideal conditions. Two-dimensional NMR signals obtained using an asymmetric π-pulse-inserted quadrupole-echo (APIQE) sequence yielded separated spectra through the skew operation of an affine transform (AT) before a Fourier transform. Modified APIQE sequences that acquire whole echo signals were fabricated, and separated PQ and PS spectra were obtained by applying a combination of AT, such as rotation and skew operations, to the signal data. These methods were demonstrated for diamagnetic Zn(CD₃CO₂)₂⋅2H₂O and paramagnetic Nd(CD₃CO₂)₃⋅1.5H₂O. Further, the dynamics of the D₂O molecule and [Co(D₂O)₆]²⁺ ion in paramagnetic CoSiF₆⋅6D₂O was analyzed based on the temperature dependence of the separated spectra.

^{获得了顺磁性固体的2} H核磁共振(NMR)的分离的纯四极(PQ)和位移(PS)光谱，并通过在理想条件下可以获得全磁化强度的简单脉冲序列进行关联。使用不对称π脉冲插入四极回波 (APIQE) 序列获得的二维 NMR 信号通过在傅里叶变换之前的仿射变换 (AT) 的偏斜操作产生分离的光谱。制作了获取整个回波信号的改进的APIQE序列，并通过对信号数据应用旋转和倾斜操作等AT组合来获得分离的PQ和PS谱。这些方法证明了抗磁性 Zn(CD ₃ CO ₂ ) ₂⋅2H ₂ O和顺磁性Nd(CD ₃ CO ₂ ) ₃ ⋅1.5H ₂ O。此外，顺磁性CoSiF ₆ ⋅6D _{2中的D 2} O分子和[Co(D ₂ O) ₆ ] ²⁺离子的动力学基于分离光谱的温度依赖性分析 O。