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Evaluation of specific capacity of poultry litter in heavy metal sorption
Water, Air, & Soil Pollution ( IF 3.8 ) Pub Date : 2021-01-16 , DOI: 10.1007/s11270-021-04984-w
Piotr Kucharski , Barbara Białecka , Anna Śliwińska , Anna Pieprzyca

The article highlights sorptive properties of poultry litter. Preliminary studies on sorption of Cd2+, Cu2+, Ni2+, Pb2+, Zn2+ ions at the concentration range of 1–1000 mg L-1 were carried out. Langmuir and Freundlich models were used to determine the potential capacities of the poultry litter. Sorption parameter outcome from isotherms exhibited the following order: Pb > Cd > Cu > Zn > Ni. During the batch adsorption experiment, a decrease of the absorbance of solutions in the UV-Vis range was observed, proportional to the increase in the concentration of metals in the solutions. This phenomenon was associated with the precipitation of complexes of fulvic/humic-like compounds and uric acid with metals. The decrease in dissolved organic carbon (DOC) concentration confirmed previous assumptions. The FT-IR spectroscopy showed significant role of uric acid in Cd2+, Pb2+, Zn2+ sorption. FT-IR measurements allowed determining the type of active sites involved in sorption, especially carboxylic groups. The findings should be helpful in soil reclamation practices with poultry litter.



中文翻译:

家禽垃圾对重金属吸附的比容评估

文章重点介绍了家禽垃圾的吸附特性。在1–1000 mg L -1浓度范围内吸附Cd 2 +,Cu 2 +,Ni 2 +,Pb 2 +,Zn 2+离子的初步研究被执行。用Langmuir和Freundlich模型确定家禽垫料的潜在能力。等温线的吸附参数结果显示以下顺序:Pb> Cd> Cu> Zn> Ni。在分批吸附实验中,观察到溶液在UV-Vis范围内的吸光度降低,与溶液中金属浓度的增加成比例。这种现象与黄腐/腐殖酸类化合物和尿酸与金属的复合物的沉淀有关。溶解有机碳(DOC)浓度的下降证实了先前的假设。FT-IR光谱显示尿酸在Cd 2 +,Pb 2 +,Zn 2+中具有重要作用吸附。FT-IR测量可以确定参与吸附的活性位点的类型,尤其是羧基。该发现应有助于家禽垫料的土壤复垦。

更新日期:2021-01-18
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