Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights,Chemical Communications

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Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights
Chemical Communications ( IF 4.3 ) Pub Date : 2021-1-5 , DOI: 10.1039/d0cc07787a
Massimo Christian D'Alterio _{1,

2,

3,

4,

5} , Claudio De Rosa _{1,

2,

3,

4,

5} , Giovanni Talarico _{1,

2,

3,

4,

5}

Affiliation

The mechanism(s) for the formation of syndiotactic PLA by the ROP of meso-LA by a chiral-Al-complex are disclosed by DFT calculations. The contributions toward stereoselectivity have been analyzed confirming the peculiar chiral recognition for stereocontrolled ROP polymerization.

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