Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines,Advanced Synthesis & Catalysis

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Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-01-21 , DOI: 10.1002/adsc.202001440
Ding Ma ₁ , Chenyang Wang ₁ , Deshen Kong ₁ , Yongliang Tu ₁ , Peng Shi ₁ , Carsten Bolm ₁

Affiliation

Palladium‐catalyzed carbonylation reactions with Cr(CO)₆ as carbonyl source are key for the preparation of N‐ynonylsulfoximines from NH‐sulfoximines and bromoalkynes. The couplings proceed at room temperature with a wide range of substrate combinations affording the corresponding products in good yields.

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