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Preparation, Properties and Growth Mechanism of Low-Cost Porous Si 3 N 4 Ceramics with High Levels of β-Si 3 N 4 Powders
Silicon ( IF 2.8 ) Pub Date : 2021-01-15 , DOI: 10.1007/s12633-021-00941-8
Haiqiang Ma , Chonggao Bao

Nowadays, porous Si3N4 ceramics are fabricated by high purity α-Si3N4 powders, resulting in a higher cost of production. To reduce cost and save energy, in this research, high levels of β-Si3N4 powders were effectively utilized to produce excellent and low-cost porous Si3N4 ceramics. The effects of high levels of β-Si3N4 powders on the microstructural evolution and properties were investigated in detail. The results suggested that, with the increase in β-Si3N4 powders from 0 wt.% to 80 wt.%, the aspect ratio of β-Si3N4 grains gradually decreased because of the anisotropic growth of grains significantly impinged by adjacent other β-Si3N4 grains. Additionally, the bending strength and dielectric constant of porous silicon nitride ceramics declined and their values were 685 MPa - 220 MPa, and 7.58–5.57, respectively, while the porosity increased from 5.9% to 28.5%. Similarly, the residual bending strength of Si3N4 ceramics degraded from 615 MPa to 172 MPa at 1000 °C for 20 h owing to the formation of SiO2 on the surface of silicon nitride ceramics after oxidizing.



中文翻译:

低成本高含量β-Si3 N 4粉末多孔Si 3 N 4陶瓷的制备,性能和生长机理

如今,多孔Si 3 Ñ 4陶瓷是由高纯度的α-制造的Si 3成Ñ 4成粉末,导致生产成本较高。为了降低成本和节省能源,在本研究中,高水平的β型Si的3成Ñ 4粉末有效地利用,以产生优良的和低成本的多孔Si 3 Ñ 4个陶瓷。高水平的β-Si组成的影响3 Ñ 4成粉末的组织演变和属性详细进行了研究。结果表明,随着增加β型Si 3 ñ 4成粉末从0重量%至80重量%,的纵横比β型Si 3Ñ 4因为由相邻的其它β型Si显著冲击晶粒的各向异性生长的晶粒逐渐下降3 Ñ 4晶粒。另外,多孔氮化硅陶瓷的抗弯强度和介电常数下降,其值分别为685 MPa-220 MPa和7.58-5.57,而孔隙率从5.9%增加到28.5%。类似地,由于氧化后氮化硅陶瓷表面上形成了SiO 2,Si 3 N 4陶瓷的残余弯曲强度在1000°C下20 h从615 MPa降低到172 MPa 。

更新日期:2021-01-15
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